Nearly 40,000 residents across Orange County were ordered to evacuate Friday after an overheating chemical storage tank at a GKN Aerospace facility in Garden Grove triggered fears of a potentially catastrophic explosion, prompting one of Southern California's largest hazardous-material emergency responses in recent years.

Local authorities said the emergency centered on a storage tank containing between 6,000 and 7,000 gallons of methyl methacrylate, an industrial chemical commonly used in plastics, resins and aerospace manufacturing. The tank reportedly began overheating Thursday evening and started venting chemical vapors into the air, forcing emergency officials to expand evacuation zones across multiple cities southeast of Los Angeles.

Evacuation orders eventually spread to portions of Garden Grove, Anaheim, Buena Park, Cypress, Stanton and Westminster as emergency crews worked through the night to prevent the tank from rupturing or exploding.

Officials warned that failure of the tank could trigger a chain reaction involving nearby chemical storage systems. Orange County Fire Authority Division Chief Craig Covey said responders were coordinating with hazardous-material specialists from across California and other parts of the country to determine how to stabilize the vessel safely.

According to Reuters and The Associated Press, firefighters deployed remotely operated cooling systems to continuously spray water onto the tank while keeping crews at a safer distance. Authorities said the cooling operation reduced internal temperatures enough to buy additional time for engineers and hazmat experts to evaluate longer-term containment strategies.

The chemical involved, methyl methacrylate, can pose serious respiratory risks when inhaled at elevated concentrations. Health officials cautioned residents about prolonged exposure to the vapors, although air-monitoring equipment had not detected dangerous chemical levels outside the immediate industrial zone as of Friday evening.

Garden Grove Police Chief Amir El-Farra said the evacuation area covered roughly 40,000 residents. Officials acknowledged that some people had refused to leave despite repeated emergency warnings.

Emergency shelters were established in Garden Grove, Anaheim and Cypress for displaced residents as schools and several nearby businesses suspended operations. Authorities also constructed containment barriers around the facility to prevent any potential chemical runoff from entering storm drains or nearby waterways.

The crisis intensified after emergency responders reportedly discovered damage to a valve connected to the tank, complicating efforts to safely release pressure from the system. The Guardian reported that updated assessments Thursday night led officials to conclude the explosion risk was significantly higher than initially believed, triggering broader evacuation orders Friday morning.

In a statement carried by The Associated Press, GKN Aerospace said "the safety of employees, residents and emergency responders remains our top priority," adding that the company was cooperating fully with local and federal authorities overseeing the emergency operation.